Friday, August 31, 2012

China, Germany to Settle More Trade in Yuan, Euros; What's That Mean for Gold, the Dollar?

Inquiring minds note China, Germany Plan to Settle More Trade in Yuan, Euros.

Germany and China plan to conduct an increasing amount of their trade in euros and yuan, the two nations said in a joint statement after talks between Chancellor Angela Merkel and Chinese Premier Wen Jiabao in Beijing on Thursday.

"Both sides intend to support financial institutions and companies of both countries in the use of the renminbi and euro in bilateral trade and investments," said the text of the statement.

It also said that both parties welcomed investments in China's interbank bond market by German banks and supported the settlement of business in the yuan by German and Chinese banks and the issuance of yuan-denominated financial products in Germany.

Announcement Mean Anything?

That's the announcement, and I have no doubt people who do not understand trade math will trump this up as if it's news of big significance.

Well, it's not. The announcement is a common sense function of math.

There is more bilateral trade between Germany and China, so fundamentally it makes sense that this agreement would be worked out. Indeed, mathematically, the markets would eventually force such an agreement.

If Germany goes back to the Deutschmark, then one should expect bilateral trade between the countries to be in Deutschmarks and Yuan.

The only relevance to the dollar is if Germany is taking away US trade with China. If not, the announcement is a meaningless function of math.

Mike "Mish" Shedlock
http://globaleconomicanalysis.blogspot.com
Click Here To Scroll Thru My Recent Post List

Disclaimer:The content on this site is provided as general information only and should not be taken as investment advice. All site content, including advertisements, shall not be construed as a recommendation to buy or sell any security or financial instrument, or to participate in any particular trading or investment strategy. The ideas expressed on this site are solely the opinions of the author(s) and do not necessarily represent the opinions of sponsors or firms affiliated with the author(s). The author may or may not have a position in any company or advertiser referenced above. Any action that you take as a result of information, analysis, or advertisement on this site is ultimately your responsibility. Consult your investment adviser before making any investment decisions.

Source: http://feedproxy.google.com/~r/MishsGlobalEconomicTrendAnalysis/~3/E2Jru3AmXlc/china-germany-to-settle-more-trade-in.html

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Building a Quality Link Profile | Niche Pursuits

Today?s post is a guest post by Tyler Herman. Tyler is a web designer, internet marketer, and has some great insights into quality link building.? As we all know with recent updates in Google and more updates sure to come, quality content and links are now vital to the success of your online business.? Tyler shares some great strategies that work.? I do have to warn you that there are some advanced tactics in here like building ?pumper sites? or buying links that are probably not a good idea for everyone.? However, Tyler is simply sharing what many companies do to rank their sites, the choice to follow any of this advice is up to you.? Overall, I think Tyler captures well the amount of effort and time it takes to truly build up a real quality link profile.? Enjoy the post!

I decided to write this post because it seems like a lot of people in the internet marketing community don?t know how to build a quality link profile. For a while now many internet marketers have been building link profiles that consisted of entirely:

  • Automated blasts of wiki links, social bookmark spam, spam comments, and spun article submissions
  • Tons of forums profiles with zero forum activity
  • Thin web 2.0s propped up with crappy links (see above) made into tiers or pyramids, or broken wheels or rainbows (made that up) or whatever ?system? is the new fad

If you are one of the people still doing this, let me be the person to burst your bubble. These types of link building practices are working less and less successfully with every Google update. Not only that, but you are setting yourself up for a penalty. It really is time to consider learning how to build a real link profile. Even if you only build 2 or three real links to your site, it may mean the difference between getting the Google hammer and surviving to see another day.

Just as a disclaimer of sorts. These techniques actually take lots of time and/or money to complete. They are not quick, or easy, and are harder to automate. Which means they probably aren?t meant for thin, niche sites, but you might find a few things here you can use, or if you decide to build a real authority site, here is how you do it.

A Solid Base of Valuable Content

If you want to rank for a truly difficult keyword, having amazing content won?t necessarily help you get there. But what it will do, is make it much easier to keep that ranking once you get there, because of longer time on page, lower bounce and exits rates, more social buzz, plus, more natural links. So if you plan on putting huge amounts of time into a site, which many of these techniques will require, you are going to want the very best content in the niche, or as close to it as you can muster.

Your entire site doesn?t have to be quality, but the handful of money pages you are ranking need to be targeted, relevant and highly useful to your users. You can probably rank a five dollar article to the first page, but it will be a lot easier to keep it there if you write better content.

One way to judge the quality and shareability of your content is to throw targeted traffic at it. An example would be Stumbleupon?s Paid Discovery. You can spend a small-ish amount of money, to get a few hundred targeted visitors to your page, and see if they thumb it up or down.

OK, quality content, duh. Lets get to the link building.

Building Highly Linkable Properties

There is only so much you can do with blog posts or pages on your site. Some content just isn?t that shareable or link worthy. Are you going to tweet a link to that article you found that helped you with your herpes outbreak? Probably not. But it isn?t just embarrassing topics, some content is simply too dry, boring or too mundane to share or link to.

So in order to build links you?ll have to build some properties that can and will get shared easily. There are lots more than even these listed, you just have to be clever and think of 1) what will people find valuable and 2) can I put a link on it. Here is a sample list:

  • Infographics
  • Web themes, plugins, and templates
  • Tutorials
  • Screencasts and Videos
  • Games
  • Web apps and mobile apps
  • Screensavers
  • Ebooks
  • Recipes
  • Ecards and greetings
  • Vectors and other free graphics
  • PDFs
  • Powerpoints and other presentations
  • Audio files
  • Other downloads
  • Meetups and webinars ? things people will signup for, talk about, blog about

But as you probably know, if you build it they won?t come. You have to get these assets in front of the people who want them. We have a few tricks to do this.

Here?s one little trick for people planing on selling products from your site like ebooks. Start out by writing one ebook, and put it up for affiliates to sell at 100% commission. You give it away for free to affiliates to make 100% of the profit. Which will bring in far more affiliates willing to hock your product, increasing the number of links and traffic heading into your site. One of the cheapest forms of advertising online is letting affiliates do it for you.

Another way to promote your assets is to pay or make an arrangement with popular blogs in the niche to promote them. Not hard to get some buzz around your freebies.

You can submit your assets to blogs, download sites, galleries, anything that will take them. They almost always give a link back to the creator of the asset. This is a nice way to get links from high PR software company sites.

Pumper Sites

The basic idea is to build or buy sites for the sole purpose of linking back, and driving traffic to your money site. You control the amount of links and the anchor text. They are tougher to maintain than 2.0s because they require their own hosting and domain and take more work to create and maintain.

If you have a money site that doesn?t get a lot of natural links on it?s own, you?ll want to build pumper sites on similar or related topics that are easier to get links and traffic for. Then you can funnel that traffic to your money site.

If your money site is in the financial niche (hard to rank), you could make a pumper site about ponzi schemes and other financial crimes. Not impossible to rank, lots of traffic potential, lots of potential for getting links. Not the greatest example but hopefully you get the idea.

Not everyone has the time or resources to build an entire blog network but 10 pumper sites can have a good effect on your money site. In order to cut down on the amount of work required, it helps to buy expired domains. Or if you have the cash, buy established sites.

Remember most sites that aren?t making any money aren?t worth a whole lot, so you can actually come up with some cheap sites if you look around hard enough. You are looking for sites in or around your niche with natural link profiles. Don?t buy sites from internet marketers. They?re generally crap sites with crap links. Look for real sites that have dropped or don?t seem to be in use any more.

Unlike what some of you are used to with 2.0s you are going to want to keep these sites updated. Having pumper site with real traffic is the goal. They may even make a little money on their own and could compete with your money site at times for some longtail keywords. Never a bad thing to have two or three dogs in the fight.

Web 2.0s

The little brother of pumper sites. I?m not going to go into this with any detail because you all should know about them already. One thing though, it is better to build 10 2.0s that you update once a month compared to 50 that you build and never touch again. It isn?t hard to turn a Tumblr, WordPress or Blogger blog into a PR2 or PR3.

There are some services available where people will build you quality 2.0?s and charge you a monthly fee to keep them updated. Can be as good as renting links if you stay with it long enough.

Renting and Buying Links

Not really a topic people bring up in public often, but lets be honest, it is still pretty rampant across the internet, especially with large corporations with large budgets. Having a couple of site wide links on a few PR4, PR5 sites will give your site a real shot in the arm. I?m not telling you to go buy links, but, if you want to compete for top keywords, your competition is probably doing it. With any blackhat strategy there is risk, but you?re all big boys and girls. Try ranking your site the legit way, if you still can?t get there, then consider buying links.

I would stay away from services on this one, as the sites those links get posted on have a footprint and a history of selling links. Instead try to contact individual sites on your own. Start out by asking for a guest posts or link exchange. If that doesn?t work put a figure out to them and see if they bite. Something like, ?Hey I noticed you have a blog roll on your site. We feel our site fits your audience perfectly. How can we get linked there??

Directories

Not as great as they once where but the big ones can still be worth it. The big ones:

Guest Posts

Another old one. If you can?t write or don?t have time, you can find lots of guest post services available around the web. You can pay anywhere from $30 to $200 per post, depending on the quality level of the writer and the PR of the blog they?ll be posting on. It can take up to a month for a guest post to get approved and up on a site but it is worth it.

One trick. Take a look at the link profile of your competitors. Eventually you?ll come across one of their guest posts. Now copy part of their author bio and do a search for it in quotes. You now have a list of the places they?ve made guest posts and you should be able to score guest posts at all these sites as well.

Authority and Social Proof

Ok, I?ve given you a few examples of ways to build authority links, and there are some more down below but first I want to talk a bit about social proof, authority and how it relates to getting people to link to you.

If you see two videos on Youtube, with the same title, same image even, but one has a million views and the other 24, you are going to watch the one with a million views 99% of the time, unless of course you?re just trying to prove me wrong. You think people can?t be gamed or duped into liking, viewing or sharing content but you are wrong.

The popular content on most social sites gets there because people paid to get it there. It can?t be total crap, but if it?s decent and promoted right you can float anything to the top. The more popular it appears, the more it get?s shared, even if the popularity was faked to start.

It really is pretty simple. The more likes, the more shares, the more views a piece of content has, the more likely real people are going to share it themselves. Humans are herd animals and tend to follow along and be validated by what the group says, thinks and does.

How many times have you not watched a youtube video because it had 70% thumbs downs or not bought something on Amazon because the reviews were bad. Those metrics can and are gamed on a regular basis, and yet we still act on them. Man we?re dumb.

I don?t think the general public is going to catch onto this for quite a while, if ever, so use this to your advantage. Social signals are incredibly easy to game. Much easier and cheaper than search these days. You can buy likes, views and shares for almost nothing. I?m willing to bet there are more bot accounts on Twitter than actual people these days.

Putting This Knowledge to Use

There are tons of very cheap ways to fake social proof and make yourself look like an authority. Never have a Facebook widget on your site unless you have a bunch of followers. For a new site, just buy them. Same thing applies for Youtube, Yelp, Google Plus, Pinterest and LinkedIn. There are plenty of services available and they?re cheap.

If you have to create your own fake accounts and share, comment on, and like your own content, do it. Or if you have a VA have them do it. Someone has to get the ball rolling.

Fake it ?til you make it

You might think this is dishonest but I guarantee all the big boys online are doing the same thing and not feeling bad about it what so ever. People want to be told what to like. So give them what they want. It might as well be you making the money instead of some other jackass.

Incentivized Sharing

This is a great way to get social shares, links, email subscribers, comments and of course, traffic. The most common method you see today is people giving away a free ebook for signing up on a list. It works the same way for getting social signups, comments, likes, any metric you are trying to build. It can also work for links. Create a contest for bloggers with a nice prize and you?ll get a lot of the contestants to naturally link to your contest page and share it via social media.

Any contest is a great way to dig up traffic and links. Just find a way to dangle that worm in front of them, and they?ll bite. You can use paid traffic, paid social promotion or give some other sort of incentive to authorities in the niche to spread the word.

Widgets and Awards

The biggest web design gallery awwwards.com gives it?s ?winners? a little badge they can place on their website that links back to awwwards.com. This tactic can work in other niches, you just have to be clever about it. Examples might be: locally owned businesses, organic or green sites, standing for a certain cause, or maybe being a part of a specific group.

Lots of people us WordPress so create custom widgets or make your awards or badges fit naturally into a widget. Instant site wide link.

Press Releases

Press releases are similar to social media but are sent out to the media in hopes they?ll publish it. Essentially a short article about your business that could be about new product launches, current promotions, community service projects, local team sponsorships. You get the idea. Once you have your release written you can pay to have it distributed. The more you pay the bigger the sites are you could have your release featured on.

If you are familiar with article marketing it is very similar. You have to write content that people want to publish. Since this is about business, go have a look at Wall Street Journal and Yahoo Finance and see what press releases they?re publishing.

If your site is or is going to be a real business, you need to be doing this. Remember social proof, this is part of it. If you need links from news organizations you can either be an expert, write for them, or get your press release published.

Community Outreach

Want to push your way into a niche. Find a way to connect with the people already established.

One way might be to create a niche-wide newsletter or curation site (perfect idea for a pumper site). You can highlight and promote the best posts, news and resources from around the web. Send it to other sites in the niche and show that you?re promoting their content. Everyone likes free promotion, and they?ll remember who you are now hopefully. So when you come calling with a favor you?ll be more inclined to get it.

These business to business connects are highly valuable.

Natural Link Building

If you weren?t aware, natural links are those from other sites who you didn?t pay, contact, or guest post for. They just liked your content, or hated it, or for some other reason felt like giving you a link.

So you have some great content, promotions, contests all that stuff ready to go. You?ve faked the social proof, making it look like there?s a bunch of buzz about your content, but you still aren?t bringing in the traffic numbers you want to see yet and you still aren?t fully ranked. You know the content is good, and people will link/share it if given the opportunity to do so. You now just have to lead the horse to water, or at least speed the process along.

Which is where paid traffic comes in. Methods include: PPC, CPA, CPM ads, retargeted ads, paid social share and promotion, paid posts, press releases, offline and traditional advertising, and so on.

Here is a good list of online advertising platforms from 3 Things.

You are probably well aware of Google ads but there are tons of other ad networks out there, and most of them are cheaper, although the quality level can be lower. You?ll just have to do some testing with each and see what your return is.

Conclusion

There is no diminishing returns with any of these methods but the more you can diversity the better off you?ll be. For a new site you might do something like this:

Set up your social profiles and buy followers. Create a few videos, a few tutorials, a couple presentations to share and promote them. Create an initial press release to announce your site. Pay to have one or two other linkable properties made and distribute them. Build or buy a couple pumper sites. Build or buy some 2.0s. Submit to a couple directories. Start putting out five guest posts a month. This alone should be a very solid link base for any website and may be even more than you need. But if you still aren?t ranking?

After that you can work on a promotion: adding in affiliates, starting to advertise, more press releases for your contests and promotions. Then begin to buy links, build more linkable properties and build additional pumper sites and 2.0s.

Hopefully you get the idea and some of this is helpful to you. Obviously, you can?t do this for a niche site making $100 a month but when you are ready to promote an authority site, these are the tools that will get it done.

============================AUTHOR BIO================================

Tyler Herman is a web designer and internet marketer. Currently, working on some free tutorials and resources geared toward small business owners. Instructing them how to build a WordPress site, create email campaign, and otherwise promote their business online, over at tylerherman.com.


How Long Tail Pro Can Help You Capture Way More Search Engine Traffic

If your business could benefit in any way from getting more search engine traffic, I have some good news.

Search engines are in love with long tail keywords! If you are able to provide relevant content targeting these long tail keywords, then you can see a dramatic increase to the amount of traffic Google and other search engines send you.

Long Tail Pro is a powerful keyword research tool that makes finding these valuable long tail keywords a breeze.

What are ?long tail keywords?? Essentially, these are words or phrases that people type into the search engines to find very specific things. Rather than searching for ?dog training? a user might search for ?how to potty train a pitbull?.

This is an example of a Long Tail Keyword. To visualize how Long Tail Keywords work...

Click to Continue Reading


Related posts:

  1. Link building for Micro Niche Sites vs. Authority Sites
  2. General Review of Link Building Strategies
  3. The Ultimate Link Building Guide for Niche Websites
  4. Building Niche Sites After the Google Penguin Update
  5. Building a Business Around Seasonal Niche Sites

Source: http://www.nichepursuits.com/building-a-quality-link-profile/

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Actor Michael Shannon to continue bad guy streak

VENICE, Italy (AP) ? U.S. actor Michael Shannon's streak of playing bad guys continues in upcoming Superman film "Man of Steel," in which he plays the superhero's nemesis "General Zod."

Shannon said he nearly "had a seizure" when director Zac Snyder tapped him for the role.

"I would've never seen that coming in a million years," Shannon told The Associated Press at the Venice Film Festival, where he attended the world premiere Thursday of "The Iceman," in which he plays a real-life Mafia hit man.

Shannon wouldn't say more about the upcoming film ? except to say "we all know what happens in Superman."

"Man of Steel" is in post-production and due for release the middle of next year.

Source: http://news.yahoo.com/actor-michael-shannon-continue-bad-guy-streak-102941315.html

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Liability-Free Outsourcing Using Time ... - Business management

Wage earners in these days aren?t only those whom you will see traveling to and out of the office, carrying out work on their very own office tables, checking out the company?s cafeteria, or going to the manager?s office to hand in their projects. The modern trend nowadays for firms is obtaining workers that they?ll connect to, not face-to-face, but virtually. We are certainly not discussing artificial intelligence machines, but we are discussing present day workers who are telecommuting for work.

Telecommuting, to state it simply is doing work at any place as well as at any time; the majority of workers who telecommute, work from their home. This type of working concept will greatly benefit the employees due to the fact he/she does not have to spend some time commuting the office, spend cash for gas, etc.

Being a business or manager working with a virtual worker, trust is amongst the most important factors which must be present within the boss-staff relationships. After all, because you trust some job onto somebody whom you cannot interact with in person, it is really vital that you?re certain that the individual is working on his task just as what you have arranged. Specifically with regards to those employers who compensate their virtual staff by the hours, they need to be much more attentive and make certain that their virtual assistant is actually working on the work and therefore the time he had worked on justify every thing that he had done with regards to that day, or for the entire wage day.

If you?re a supervisor and has the similar difficulty as stated above, be troubled no more. You can make use of Time Management Software to keep an eye on your staff?s each action while doing the job on the internet. These kinds of employee time management software have several qualities yet they all hold one specific objective, to be sure that your telecommuting personnel is really working on the task and that you will just pay him what?s rightfully payable for the job he have accomplished.

The common issue many employers have when employing an individual on line is: without any a Web Based Time Management Software, a number of virtual workers often times overcharge their employers. For example, your personnel has worked for just a total of 30 hours and yet he billed you for 50 hours instead. In case you didn?t have the appropriate software to check his working activity, you may end up paying a lot more instead of what you truly should. Therefore, to protect your welfare as an employer, it is only acceptable to make sure that both sides are receiving what?s expected from the project.

Use a Time Management Software and you?ll definitely realize that employing a virtual staff is not that high-risk and difficult after all. As a matter of fact, it will help make work better for you and your employee and more trust will likely be developed bringing about greater work output. You?ve probably heard of this type of application before and there are lots of of them available today. So, if you are moving towards productiveness and success for your internet work and company, use a time management software which will work for you perfectly.

About the Author

More information about this writer?s blog HERE

Source: http://www.emmosaics.com/2012/08/Liability-Free-Outsourcing-Using-Time-Management-Software/

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StatusBulletin Shrinks Your Notifications into the Status Bar and Scrolls Automatically When They're Too Long [Jailbreak]

StatusBulletin Shrinks Your Notifications into the Status Bar and Scrolls Automatically When They're Too LongiOS: (Jailbroken): Your iPhone's notifications can get in the way sometimes get in the way, but a clever jailbreak called StatusBulletin will shrink them down to the size of your status bar. On top of that, if the message doesn't fit it will scroll it automatically so you can read the entire thing.

While smaller, simpler notifications is the primary purpose of StatusBulletin, it also offers a few settings to change the banner style and show and hide message titles based on the type of notification. You can even change message titles for individual apps yourself.

If you want to check it out, StatusBulletin is available for free on Cydia in the ModMyi repo.

StatusBulletin (Free) | ModMyi via Addictive Tips

Source: http://feeds.gawker.com/~r/lifehacker/full/~3/46hTVjeDVxI/statusbulletin-shrinks-your-notifications-into-the-status-bar-and-scrolls-automatically-when-theyre-too-long

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Tuesday, August 21, 2012

Rosie O'Donnell says she had heart attack

By Kurt Schlosser, TODAY

Rosie O'Donnell tweeted a link to her personal website Monday that gave details about a heart attack she says she suffered last week.

In a post titled "my heart attack" on Rosie.com, the comedian starts by saying it's a sunny Monday and she's happy to be alive. She goes on to describe events that started last Tuesday with helping an "enormous woman" out of her car in a parking lot in Nyack, N.Y.

O'Donnell says that a few hours after helping the woman she felt a pain in her chest and that both of her arms were sore. She thought she strained a muscle and went about her day, she writes. Later she became nauseous, hot and clammy and says she threw up.

O'Donnell says she looked up symptoms for women's heart attack on the Internet and took some aspirin. She did not call 911 and in her post cites a statistic: "50% of women having heart attacks never call 911, 200,000 women die of heart attacks every year in the US."

Related:?O?Donnell?s heart attack: classic, for a woman

Mary Altaffer / AP

After a visit to a cardiologist the next day, O'Donnell says it's a miracle she was not one of the women who suffer a fatal heart attack. She says her LAD was 99 percent blocked and a stent was put in. (In the heart, the left coronary artery usually divides into two branches, known as the left anterior descending (LAD) and the circumflex (Cx) coronary arteries).

O'Donnell's rep Cindi Berger confirmed to NBC News that O'Donnell did write the post and that she's "now home and resting comfortably."?People magazine?reported that Berger said,?"She is very, very lucky."

O'Donnell concludes her blog post by urging women to know the symptoms and to call 911. "save urself," she says.

More Entertainment news:

Source: http://todayentertainment.today.msnbc.msn.com/_news/2012/08/20/13379684-rosie-odonnell-says-she-suffered-heart-attack-last-week?lite

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Sunday, August 19, 2012

Know Your Consoles: The Atari 2600 ? What's Your Tag?

The history of video game consoles stretches back in a rich tapestry of failures and success, hits and duds. In this article of the weekly series, we?ll be taking a look at the Godfather of modern video game systems; the revolutionary Atari 2600.

Lifespan

Originally known as the Atari Video Computer System, the console was released in October 1977 by Atari, Inc. With the price of $199, accompanied by by two cartridges and the game Combat. However, due to an ongoing price battle between Atari Inc. and Channel F?s Video entertainment system, the Atari VCS sold poorly in it?s first year. Only 250,000 systems were sold.

Despite further losses in 1978, Atari Inc. managed to gain dominance in the video game market and due to programmers pushing the system?s hardware the Atari sold one million units in 1979.?Incredibly, Atari systems are still being sold and games still being developed. Overall the Atari 2600 has sold over 30 million consoles and hundreds of millions of games.

Technical Stuff

The Atari system used microprocessor-based hardware, and it?s game cartridges contained their own game code. The system was limited to 4kB of external memory space, and ran on the MOS technology 6057 with 13 memory pins. At it?s time, it was credited as one of the most complex machines to program. It?s standard controller was a joystick, although the system supported the use of paddles and keyboards. This flexibility allowed players to have their own preffered set up.

?

Notable Games

Source: http://whatsyourtagblog.com/2012/08/18/know-your-consoles-the-atari-2600/

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India's Vanya Mishra loses Miss World title

Ordos (China), Aug 18 : India's 12-year-long dry run at the Miss World continued with Vanya Mishra losing out in the finals of the 2012 beauty pageant here Saturday.

The 20-year-old Chandigarh girl entered the top seven of the Miss World competition, being held in Dongsheng Fitness Center Stadium here, but lost to the Chinese contestant.

Source: http://www.mynews.in/News/indias_vanya_mishra_loses_miss_world_title_N474856.html

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COMMON MYTHS ABOUT ALCOHOL | Health - Tips

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Source: http://healthtips-sastha.blogspot.com/2012/08/common-myths-about-alcohol.html

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Saturday, August 18, 2012

Gunman in Texas shootout fired more than 65 rounds

Associated Press

Posted on August 18, 2012 at 1:03 PM

HOUSTON -- Police say a gunman who was among three people killed in a shootout at a home near Texas A&M University earlier this week fired more than 65 rounds during the incident.

New details about the shooting in College Station were made public Friday as police released a timeline of Monday?s deadly incident.

Police found four weapons in the home of the gunman, Thomas Alton Caffall III, after he was killed. They included a handgun Caffall removed from a constable who was killed. Also found in the home were a sniper rifle, an assault rifle and a bolt-action rifle.

Police say Caffall fatally shot Brazos County Constable Brian Bachmann and bystander Chris Northcliffe. He also wounded three officers and a female bystander.

Funerals for Bachmann and Northcliffe are set for Saturday.

Source: http://www.khou.com/home/Gunman-in-Texas-shootout-fired-more-than-65-rounds-166644746.html

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Republicans mock Obama for softball interviews

Republicans are taking President Obama to task for evading public questioning by the White House press corps for more than eight weeks, while instead granting a series of interviews to entertainment media outlets with whom he discussed largely frivolous subjects.

A new web video by the Republican National Committee asks, "why is Obama avoiding the White House press corps?" It features a clip of Obama campaign spokesman Ben LaBolt insisting that the president has fielded substantive questions during interviews with local media on his swings through battleground states.

"I wouldn't assume that if he's in a local market that the reporters' questions will be any less serious," LaBolt says.

Cue the KOB-FM radio interview with Obama that aired this morning in Albuquerque, N.M.

The president fielded no substantive questions on news of the day or matters of policy. Instead, he discussed his favorite type of chili, iPod playlist, a desired superpower, and Carly Rae Jepsen's hit single, "Call Me Maybe."

An on-screen graphic in the RNC ad reads: "THIS IS NOT A PARODY."

Asked about Obama's streak of lighter interviews, including sit-downs with Entertainment Tonight and People Magazine, White House spokesman Josh Earnest said today that the president has also been accessible to members of the local and national press, including at an official Oval Office bill signing in the past week.

"The president has spent a lot of time answering questions from journalists all across the country. The president's spent a lot of time talking publicly about the issues that he thinks are at stake in this election and are worthy of an important political debate about the future of the country. And that is something that he feels a responsibility to do," he said.

As for whether the interviews risk making the president appear out of touch with the nation's serious economic issues, Earnest dismissed the notion.

"Anybody who has listened to what the president has said on the - on the campaign trail - the president over the course of this week has done three and four events a day where he's talking about issues that he thinks are at the top of the political agenda, that are so critical to the future of this country," he said.

Obama last took questions from the White House press corps at a news conference during the G20 summit in Chicago in June. His last formal White House news conference was on March 6.

Get more pure politics at ABC News.com/Politics and a lighter take on the news at OTUSNews.com

Also Read

Source: http://news.yahoo.com/republicans-mock-obama-softball-interviews-185024556--abc-news-politics.html

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GuidoFawkes: Lovers of paradox will be amused to note that Twitter has verified this is the real @GuidoFawkes with that blue tick thing. Amused me.

Sorry, Readability was unable to parse this page for content.

Source: http://twitter.com/GuidoFawkes/statuses/236737449810882560

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Friday, August 17, 2012

London Firings Seen Surging as Financial Firms Add New York Jobs

Financial firms in London, besieged by Europe?s sovereign-debt crisis, probably will shrink their workforce this year, snapping a hiring rebound from 2008?s credit crisis as New York?s industry ekes out job growth.

Banks, insurers and other financial-services firms may eliminate a total of about 3,000 jobs across greater London as companies in the New York region add 9,000, according to U.K.-based researcher Oxford Economics Ltd.

London?s proximity to the debt crisis is undermining the city?s efforts to gain on its transatlantic rival. While Wall Street also is suffering from a global slowdown in trading and deal-making, North American banks are benefiting from a surge in consumer lending.

?Europe is still going into deeper waters, which would make London less attractive, more risky? for employers, said John A. Challenger, chief executive officer of Chicago-based Challenger, Gray & Christmas Inc., which advises firms on workforce reductions. ?Momentum for the lead has turned back toward New York and the U.S.?

Reductions will be particularly acute in London?s wholesale financial-services industry, which may cut 25,200 positions this year, according to the Centre for Economics and Business Research Ltd.

HSBC Holdings Plc, Europe?s biggest bank by market value, announced plans in April to eliminate 3,167 positions in its home U.K. market, mostly in senior and middle management, under a plan to rein in costs. Frankfurt-based Deutsche Bank AG, Germany?s largest lender, said last month it will cut about 1,900 jobs, including 1,500 in its investment bank, which has operations in London and New York.

Hiring Spree

Financial-services firms and insurers in both cities had been hiring. London added about 28,000 jobs in the two years ended Dec. 31 and 13,000 more in this year?s first quarter, reaching 382,000, according to the most recent figures from the U.K.?s Office for National Statistics.

New York City gained 12,500 during those two years and 5,500 more through July, according to the New York State Department of Labor. About 446,200 people now work in the financial industry, the data show.

U.S. lenders benefited from a 125 percent jump in mortgage- banking income, which amounted to $13.7 billion in the year?s first half, according to Inside Mortgage Finance, an industry publication. Credit cards and other forms of revolving debt held by U.S. commercial banks rose 0.8 percent to $601.4 billion in July from a year earlier, Federal Reserve data show.

Lucrative Packages

That belies the past year?s turmoil across the investment- banking industry, where workers typically reap the most lucrative pay packages. The trading and deals slump, as well as stiffer capital rules and limits on risk-taking, have left securities firms on both sides of the Atlantic facing questions about whether they?re locked in a so-called secular, or lasting, decline.

Average daily equity-trading on the largest U.S. exchanges has fallen 15 percent this year so far, compared with the same period in 2011. In London, the figure is down 10 percent on 2011. Pending and completed mergers and acquisitions in the nation dropped 35 percent to about $575 billion. That compares with Europe?s 21 percent slide to $505 billion.

The slowdown has prompted investment banks to pare jobs in their securities divisions. New York-based Citigroup Inc. will eliminate about 350 positions in its securities unit, people with knowledge of the plan said last month. Goldman Sachs Group Inc., which generated 58 percent of first-half revenue from sales and trading, eliminated 20 to 30 jobs in that division this week, a person briefed on the matter said.

Boutique Firms

?The bigger guys have an oversupply of people,? said Gustavo Dolfino, a former UBS AG banker who?s now CEO of WhiteRock Group LLC in New York, which advises on employment in financial services. Meantime, boutique firms and regional lenders are targeting talent in areas such as health-care, technology and energy banking, he said.

New York firms with hiring aspirations include Cantor Fitzgerald LP, which is adding 200 employees this year and may hire 800 more for its broker-dealer in coming years, CEO Shawn Matthews said in an interview in June.

Toronto-Dominion Bank, Canada?s No. 2 lender by assets, plans to add about 50 branches in New York over the next four years as part of a strategy to rank among the area?s top three lenders by number of locations. Aflac Inc., the Columbus, Georgia-based insurer with the talking-duck mascot, opened an investment-management office in Manhattan in May.

Many of the new jobs aren?t ?the same type of high-level, Wall Street, get-a-Porsche-and-Ferrari-type jobs that everyone was trying to put themselves in the position to get a couple years ago,? said Adam Kahn, managing partner at Odyssey Search Partners, which recruits executives for Wall Street firms.

New Talent

Some large banks are offsetting senior-staff reductions by recruiting less-expensive workers. New York-based Goldman Sachs, seeking to cut $500 million of costs, expects its workforce to feature a greater proportion of junior employees by year-end, Chief Financial Officer David A. Viniar, 57, said July 17.

?Wall Street is tilting toward younger, up-and-coming talent,? Kahn said. ?Some of the folks that have a lot of experience and are paid a lot more money have been downsized in a cost-cutting effort.?

Finding a job has been toughest for people seeking middle- management positions, while lower ranks, such as associates and analysts, are faring better, WhiteRock?s Dolfino said.

London?s financial industry probably will rejoin New York?s in adding jobs next year, and growth will be about 1 percent in both places, according to Oxford Economics. London?s financial district may regain almost 1,300 jobs in 2013, CEBR said in May when releasing what it called ?a sharp downward revision? to its forecast.

The change ?shows how the financial crisis is hitting the City,? the firm?s CEO, Douglas McWilliams, said at the time.

? Copyright 2012 Bloomberg News. All rights reserved.

Source: http://www.moneynews.com/FinanceNews/London-Financial-Jobs-firings/2012/08/17/id/448884

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Google, Samsung, HTC said to join Apple in bid for Kodak patent trove

?Kodak?s auction of intellectual property has yet to produce a sale. But it has had one unlikely result: turning the fiercest rivals in the global patent battle into potential collaborators,? Mike Spector, Ashby Jones and Dana Mattioli report for The Wall Street Journal.

?In recent days, the rival technology giants and patent-hoarding firms that had mounted competing bids for the portfolio have joined forces, people with knowledge of the negotiations said?a move that could take the patents off the market at a price below what Eastman Kodak Co. had hoped to raise in a competitive auction,? Spector, Jones and Mattioli report. ?The bidding group brings together a raft of strange bedfellows. It includes Apple Inc. and Google Inc., fierce competitors in the global smartphone market? ?People familiar with the matter said the consortium bidding on Kodak?s patents also includes Samsung Electronics Co., LG Electronics Inc. and HTC Corp., all companies building smartphones based on Google software.?

?Negotiations and the bidding group?s composition are fluid, the people said. If the consortium reaches a deal to buy some or all of Kodak?s patents, they would essentially be kept out of any one company?s hands and could prevent consortium members from using them in litigation against each other. A deal, however, could also attract attention from federal antitrust regulators,? Spector, Jones and Mattioli report. ?A deal for the entire portfolio?one of many options under discussion? could fetch more than $500 million based on recent negotiations, people familiar with the process said. That is well above opening bids when the auction started last week, but far below the $2.2 billion to $2.6 billion Kodak at one point said the patents could be worth.?

Read more in the full article here.

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In wake of Nortel patent auction loss, Google general counsel calls for patent reform ? July 26, 2011
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Apple, Google gird for bidding war over InterDigital patent trove ? July 20, 2011
U.S. and Canadian courts approve sale of Nortel patent trove to Apple-led ?Rockstar? consortium ? July 11, 2011
How Apple led the high-stakes Nortel patent win against Google, sealing Ballmer?s promise ? July 10, 2011
Google?s Schmidt worried and disappointed over Apple consortium?s Nortel patent win ? July 8, 2011
RUMOR: Apple gets outright ownership of Nortel?s LTE (4G) patents ? July 5, 2011
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Leaked bids show how Apple-led ?Rockstar? beat Google to Nortel patents ? July 2, 2011
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Intel gets antitrust approval to bid on Nortel patents ? June 24, 2011
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Apple, Intel among bidders for Nortel patent trove ? June 17, 2011
Nortel delays patent auction one week citing significant interest ? June 16, 2011
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Apple stock hits new high after 4-month dip

(AP) ? Apple's stock has hit a new high after a four-month swoon, as investors are looking ahead to the release of a new iPhone model, and possibly a smaller iPad.

Already the world's most valuable company, Apple Inc. saw its stock hit $644.13 in morning trading Friday, before retreating to $642.

The previous high for the stock was $644, hit on April 10.

Apple has a market value of $602 billion, almost 50 percent higher than No. 2 Exxon Mobil Corp. at $408 billion.

Apple's stock fell last month after the company's earnings report for the April-June quarter showed the slowest growth in more than two years. It was only the second time in 10 years that Apple had missed analyst expectations.

Associated Press

Source: http://hosted2.ap.org/APDEFAULT/f70471f764144b2fab526d39972d37b3/Article_2012-08-17-US-TEC-Apple-Stock/id-6b964d71b56541cc9596d442d66cc642

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Thursday, August 16, 2012

University Art Museum - Random Lengths News

By Andrea Serna

When Chris Scoates arrived in Long Beach there was an expectation that he would create an innovative environment at the Cal State Long Beach campus museum. He has not been disappointed.

As the second director of the University Art Museum, he has built a firm reputation as a published author and curator of exhibitions in a wide variety of genres.

Since 2005, Scoates has created a white hot art museum, buried in the middle of the Cal State campus. Struggling with the constraints of a troubled state budget crisis, his team has managed to bring world class exhibitions to Long Beach.

Scoates? interest in the merging of technology and contemporary art disciplines has formed an exciting collaboration with a diverse group of artists, musicians and techno centric creatives.

Early in his tenure merging art and technology bought Scoates to the 5D project, a global community of multi-disciplinary creators.

In 2009, the University Art Museum presented Brian Eno?s 77 Million Paintings. The avant garde musician was one of the forerunners of ambient music. His installation of light and sound premiered at the Venice Bienalle in 2007. The University Art Museum followed with Lou Reed?s Metal Machine. This project was the culmination of a decades long vision for Reed. The 1975 album, critically rejected by the music industry and the musicians own fans, is now considered a seminal forerunner of contemporary sound art.

?Part of the reason I did the Lou Reed Metal Machine show is that Music for Airports, Brian Enos album, and Metal Machine both came out in 1975,? Scoates said. [Actually, Music for Airports came out in 1978, but was based on the music-making approach pioneered on Discrete Music in 1975].

?They are both about generative systems, but very different sound. So the Lou Reed, and the Brian Eno projects sort of bookend, an interesting trajectory of new experimental sound pieces.?

This year the International Associations of Art Critics recognized UAM for ?Best Show in a University Gallery? for its 2010 exhibition ?Perpetual Motion: Michael Goldberg.? The other winner in this category was Dartmouth University?s Hood Museum. Scoates notes that as he traveled to accept the award, he found himself surrounded by people from the New York Metropolitan Museum, The Whitney Museum and the Guggenheim. Undeniably a heady crowd for the director of a university museum.

While strongly stating that the art world needs to expand beyond historical models, Scoates does not intend to ignore the historical context of traditional media. The UAM was the recipient of an endowment from the Hampton family that has allowed them to build several major exhibitions, ?Perpetual Motion? being a prime example.

?We were gifted 85 second generation abstract expressionist works. Five Lee Krasners, Adolph Gottleieb, Michael Goldberg, Melan Resnick, a really fabulous collection. It?s an educational opportunity and creates a foundation to build upon,? Scoates explained.

This means other collectors are also willing to work with the museum because of the collection, Scoates noted.

In the fall, UAM?s show ?From the Vault? will primarily be drawn from Perpetual Motion collection.

?It allows us to balance the other crazy things we are doing, like the technology projects, the Lou Reed and Brian Eno,? Scoates said. ?It allows us to provide an interesting balance.?

?It allows people to think differently about what they are hearing in some of the sound works and what they are seeing in some of the paintings. They are actually not that far from each other.?

The University Art Museum has struggled with a familiar challenge. Internationally known but locally obscure. Somewhat ironically, many of the CSULB students graduate without ever visiting the award winning museum. In addition the location, in the heart of one of California?s busiest campuses, has sometimes proven to be a hurdle for the local Long Beach residents, a city that has tried to create an identity as an arts community with mixed results.

The director strongly believes that the museum world is changing radically.

?New technologies have allowed us to blur boundaries. New ideas of experience and interaction, which I don?t think we can continue to ignore.?

The University Art Museum and its director has followed through on that vision.

Source: http://www.randomlengthsnews.com/blogs/ACE/2012/08/university-art-museum/?utm_source=rss&utm_medium=rss&utm_campaign=university-art-museum

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The case for shutting up: Wasted time at work

Bruce Ayres / Getty Images

Web surfing? Facebook? Online shopping? No. The water cooler, or its equivalent, kills the most time.

By Michelle V. Rafter, Today contributor

Technology may be revolutionizing the workplace, but old-fashioned distractions like meetings and chatting with co-workers are still considered the biggest office time-wasters.

That, at least, is the conclusion of a survey of office workers, released Thursday by TrackVia, a Denver-based software company.

Office chit-chat ranked as the No. 1 work distraction, the top choice of 14 percent of those surveyed, while meetings and computer problems followed close behind at 11 percent each.

Other time wasters mentioned by survey respondents:

  • Surfing the web
  • Dealing with office politics
  • Addressing misunderstandings with co-workers
  • Using social media
  • Checking email
  • Following company rules and procedures

It?s no surprise employees see going to meetings as a major obstacle to accomplishing their work-day goals, says productivity expert Laura Stack.

?A lot of people feel like they spend their entire day in meetings,? says Stack, a Denver-based speaker and author who leads 80 to 100 productivity training sessions a year.

In her experience with clients, however, employees waste far more time checking email, instant messages and social media like Facebook -- what she calls ?tech time? -- than dealing with computer problems or on other non-critical tasks. ?You could sit in your inbox all day and at the end of the day say, ?Where?d all my time go??? Stack says.

Holly Witt, a Portland, Ore., insurance account executive, says social media is her biggest time waster, especially Facebook.

?I keep telling myself to deactivate the account and I am almost there,? she says.

Slightly more than half of employees surveyed (51 percent) say they waste up to two hours a week on tasks that aren?t work related or don?t help them ?get real work done.? Approximately 11 percent say they waste 6 to 9 hours on nonessential tasks, and close to 4 percent said they waste 10 to 19 hours during the work week, according to the survey.

The survey of 300 workers, conducted this month by Amplitude Research, has a margin of error of about 6 percent.

Source: http://lifeinc.today.msnbc.msn.com/_news/2012/08/16/13302788-the-case-for-shutting-up-how-we-waste-time-at-work?lite

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Asian stocks up as hopes rise for China to act

BANGKOK (AP) ? Asian stock markets were mostly higher Thursday, after China's premier reportedly said that he believes the country's current economic picture leaves room for the central bank to take action to help spur growth.

Premier Wen Jiabao, during a visit to eastern China earlier this week, was quoted by the official Xinhua News Agency as saying that a stable employment environment and an easing of inflation left room for "monetary loosening."

That raised expectations that the People's Bank of China would either lower the ratio of funds that banks must hold as reserves, known as the reserve requirement ratio, or lower interest rates. The bank so far this year has lowered both twice in an effort to boost lending and spur growth.

Japan's Nikkei 225 index rose 1.5 percent to 9,056.79. Hong Kong's Hang Seng added 0.3 percent to 20,109.63, while Australia's S&P/ASX 200 added 0.6 percent to 4,308. Benchmarks in Singapore and Taiwan also rose.

South Korea's Kospi was marginally lower at 1,956.06. Benchmarks in mainland China and New Zealand also fell.

Investors also think the European Central Bank will announce new policy measures in the coming weeks. The ECB is expected to restart its bond-buying program in order to hold down borrowing rates of Italy and Spain.

"The lack of negative surprises related to the Euro crisis so far this week has allowed for a mild mood of risk appetite, as hopes for policy action in a few weeks time remains high," analysts at Credit Agricole CIB in Hong Kong wrote in a market commentary.

U.S. stocks closed mostly higher Wednesday after signs that the economic recovery is on track, albeit at a slow pace.

In a sign that of improving manufacturing after a weak spring, the Federal Reserve reported that U.S. industrial production increased last month as factories made more cars, computers and airplanes.

Also, consumer prices were unchanged in July from June, as a small drop in energy costs offset slightly higher food prices. The consumer price index hasn't changed since March, which means that inflation is in check.

Lower inflation gives the Fed more leeway to launch new programs intended to rekindle the economy. The Fed signaled at a meeting in late July that it is ready to act if growth and hiring stays weak.

The Dow Jones industrial average fell less than 0.1 percent to 13,164.78 on Wednesday. The broader Standard & Poor's 500 index gained 0.1 percent to 1,405.53, and the Nasdaq composite index lost 0.5 percent to 3,030.93.

Benchmark oil for September delivery rose 22 cents to $94.55 per barrel in electronic trading on the New York Mercantile Exchange. The contract rose 90 cents to finish at $94.33 per barrel Wednesday in New York, its highest level since mid-May.

In currencies, the euro rose to $1.2294 from $1.2290 in New York late Wednesday. The dollar rose to 79.17 from 78.88 yen.

Source: http://news.yahoo.com/asian-stocks-hopes-rise-china-act-024048187--finance.html

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Two birthday cakes for Julia Child

When you have several cooks in the kitchen, things go faster but they can also go awry. What happened when we tried to bake two sponge cakes in honor of Julia Child's 100th birthday.

By Kendra Nordin,?Kitchen Report / August 15, 2012

American television chef Julia Child shows a salade nicoise she prepared in the kitchen of her vacation home in Grasse, southern France, on August 21, 1978.

AP

Enlarge Photos

Julia Child?s birthday is August 15 and this year marks her 100th.?I decided I wanted to honor Julia by baking a birthday cake for her on my birthday, just a few days before, using a recipe or two from one of her many collections.

Skip to next paragraph Kendra Nordin

Staff editor

Kendra Nordin is a staff editor and writer for the weekly print edition of the Monitor. She also produces Stir It Up!, a recipe blog for CSMonitor.com.

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I must admit that while I am an admirer, I am not a Julia Child disciple. Even though I own ?The Way to Cook? with this inscription: ?Christmas love to Kendra, from Mom, 1998,? I remain somewhat intimidated by it.

My birthday this year fell on a Sunday, and the weekend seemed like the perfect opportunity to host a little backyard picnic with some friends, offered in a kind of casual elegance that describes August. My mom?s house on the Cape is the ideal setting for this kind of thing. More so than me, I think my mom and Julia would have been good friends, had they ever met. A intellectual fervor and the tendency to not sweat the small stuff are characteristics they share.

On Sunday morning, however, a steady rain drummed on the roof. Jenna, Gretchen, and I could all hear it from our beds tucked under the eaves. A text arrived from my brother who would be on his way soon with his family to join us in the backyard. ?Is there a Plan B??

No, there was not.

After glumly deciding against a swim in the pond, Jenna, Gretchen, and I set to work on not one, but two cakes: Orange and Almond Sponge Cake and Reine de Saba (Queen of Sheba) from Julia's ?Mastering the Art of French Cooking.?

Cooking, at least successful cooking, tends to be a solitary affair. A cooking party, which this turned out to be, is more fun, and more chaotic. When you have many cooks, things go faster and they can also go awry. They did.

I sat at the long kitchen table and called out instructions as Jenna and Gretchen tried to navigate an unfamiliar kitchen. The electric mixer wasn?t working, so Jenna beat the egg whites by hand (a strong swimmer?s arm is good for this).

Another setback, the sudden arrival of guests ready for lunch was a distraction in our work flow and more ground almonds went into the cake than necessary. We were nowhere near ready.

Another distressing discovery: I had called out the instructions for the wrong cake ? I had wanted to make a Queen of Sheba cake that required no filling and had instead skipped ahead a page and was directing a Chocolate Sponge Cake without realizing it. Two sponge cakes was not in the original plan. But the chocolate sponge cake and Queen of Sheba are so similar in their ingredients it hardly mattered, we thought, except for one thing. The sponge cakes didn?t rise.

Maybe it was the rain. Humid Cape air is a constant presence in the summer as it blows in one window and out the next. It?s one reason why things are so causal on the Cape. Everyone slumps around in wrinkled clothes and tugs at swollen doors because that?s the way it is. The kitchen, with its low raftered ceiling and bones dating back to 1840, has no air conditioner. Or maybe we beat the egg whites too hard. Or maybe we shouldn?t have used unbleached cake flour.

But this is what I love about Julia?s example. I don?t think she?d worry too much over our flat sponge cakes. She says to?master?cooking, and that means doing things many times until it clicks. It also means don?t get hung up on a failed dish. You don?t master something on the first try, after all. Maybe on the 10th or 20th try. I think Julia would be satisfied that we had tried at all.

?The measure of achievement is not winning awards,? Julia once remarked. ?It?s doing something that you appreciate, something you believe is worthwhile. I think of my strawberry souffle. I did that at least twenty-eight times before I finally conquered it.?

Source: http://rss.csmonitor.com/~r/feeds/csm/~3/OghsdLAn47Y/Two-birthday-cakes-for-Julia-Child

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Behaviors of the tiniest water droplets revealed

ScienceDaily (Aug. 15, 2012) ? A new study by researchers at the University of California, San Diego, and Emory University has uncovered fundamental details about the hexamer structures that make up the tiniest droplets of water, the key component of life -- and one that scientists still don't fully understand.

The research, recently published in The Journal of the American Chemical Society (JACS), provides a new interpretation for experimental measurements as well as a vital test for future studies of our most precious resource. Moreover, understanding the properties of water at the molecular level can ultimately have an impact on many areas of science, including the development of new drugs or advances in climate change research.

"About 60% of our bodies are made of water that effectively mediates all biological processes," said Francesco Paesani, one of the paper's corresponding authors who is an assistant professor in the Department of Chemistry and Biochemistry at UC San Diego and a computational researcher with the university's San Diego Supercomputer Center (SDSC). "Without water, proteins don't work and life as we know it wouldn't exist. Understanding the molecular properties of the hydrogen bond network of water is the key to understanding everything else that happens in water. And we still don't have a precise picture of the molecular structure of liquid water in different environments."

Researchers know that the unique properties of water are due to its capability of forming a highly flexible but still dense hydrogen bond network which adapts according to the surrounding environment. As described in the JACS paper, researchers have determined the relative populations of the different isomers of the water hexamer as they assemble into various configurations called 'cage', 'prism', and 'book'.

The water hexamer is considered the smallest drop of water because it is the smallest water cluster that is three dimensional, i.e., a cluster where the oxygen atoms of the molecules do not lie on the same plane. As such, it is the prototypical system for understanding the properties of the hydrogen bond dynamics in the condensed phases because of its direct connection with ice, as well as with the structural arrangements that occur in liquid water.

This system also allows scientists to better understand the structure and dynamics of water in its liquid state, which plays a central role in many phenomena of relevance to different areas of science, including physics, chemistry, biology, geology, and climate research. For example, the hydration structure around proteins affects their stability and function, water in the active sites of enzymes affects their catalytic power, and the behavior of water adsorbed on atmospheric particles drives the formation of clouds.

"Until now, experiments and calculations on small water clusters have agreed very well up to the pentamer (in chemistry, meaning molecules made of five monomers) but the energetic ordering of the low-lying isomers of the hexamer has always been controversial," said Paesani.

Added corresponding author Joel M. Bowman, with Emory University's Department of Chemistry and the Cherry L. Emerson Center for Scientific Computation: "Ours are the first simulations that use an accurate, full-dimensional representation of the molecular interactions and exact inclusion of nuclear quantum effects through state-of-the-art computational approaches. These allow us to accurately determine the stability of the different isomers over a wide range of temperatures ranging from 0 to 150 Kelvin, (almost minus 460 degrees to about minus 190 degrees Fahrenheit)."

While the prism isomer was identified as the global minimum-energy structure, the quantum simulations predicted that both the cage and prism isomers are present in nearly equal amounts at extremely low temperatures, researchers found. As the temperature increased, more cages, and then book structures, began to appear.

Researchers used SDSC's new data-intensive Gordon supercomputer as well as SDSC's Triton compute cluster to conduct the data-intensive simulations.

"Our simulations took full advantage of Gordon distributing the computations over thousands of processors," said Volodymyr Babin, a researcher with UC San Diego's Department of Chemistry and Biochemistry. "That kind of parallel efficiency would be hardly achievable on a commodity cluster. The scalability of our computational approach stems from the combination of a state-of-the-art simulation technique (replica-exchange) with path-integral molecular dynamics."

Babin said the team is currently working on extending this methodology to study the microscopic origins of the unusual properties of liquid water and ice aiming to assess quantitatively the role played by nuclear quantum effects in the topology of the water phase diagram. This project involves a huge number of data-intensive quantum chemistry computations that are only feasible on supercomputers of the same class as Gordon, he added.

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Journal Reference:

  1. Yimin Wang, Volodymyr Babin, Joel M. Bowman, Francesco Paesani. The Water Hexamer: Cage, Prism, or Both. Full Dimensional Quantum Simulations Say Both. Journal of the American Chemical Society, 2012; 134 (27): 11116 DOI: 10.1021/ja304528m

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